The present invention belongs to the field of refractory material, specially, it is suitable for producing phosphoric acid combined high-aluminium pouring material. It is characterized by that it uses electrocast spinel as coagulation accelerator or phosphoric acid combined pouring material, its main raw material is a high-grade high-alumina, and its secondary raw material is electrocast magnesia-alumina spinel and phosphoric acid. Said inention is easy to construct and easy to remove form, and has higher strength, after the form of removed for 3 days, it is water resistant. |