The fludizied-bed catalyst for preparing acrylonitrile by means of propylene ammonia oxidation contains SiO2 carrier and the following composite: Mo12BiaFebNicRedNaeXfYgOm, where X is at least one selected from Li, K, Rb, Cs, Sm or Tl, and Y is at least one selected from Co, Mg, Mn, Ca, Ce, La, B, P or Cr. Said catalyst is specially applicable to use under the conditions of low reaction temp., low air/propylene ratio, high reaction pressure and high propylene load. It can ensure high yield of acrylonitrile. |