Original document(19 pages)  中文版
    The invention is an oligomerization process. A catalyst, a lower olefin, and a process medium are provided. The lower olefin is reacted in the presence of the catalyst to produce a product stream comprising a higher olefin product and a catalyst residue dispoersed in the process medium. The resulting product stream is treated with a quenching material. The quenching material can be an aliphatic primary amine, an aliphatic secondary amine, an alcohol, or a combination of those materials. Amine quenching materials have been found to generate few or no hydrogen halides when used to quench oligomerization catalysts. Alcohol quenching materials can generate hydrogen halides in use. This problem can be alleviated by treating the product stream with a stabilizing material that forms a stable hydrogen halide salt. Exemplary stabilizing materials include aliphatic amines, aromatic amines, and metal salts of amides, butoxides, or carboxylic acids.
Application Number
申请号
00816222 Application Date
申请日
2000.12.27
Title 名称 Processes for preventing generation of hydrogen halides in oligomerization product recovery system
Publication Number
公开号
1399620 Publication Date
公开日
2003.02.26
Approval Pub. Date Granted Pub. Date
International Classification 分类号 C07C2/06;C07C2/08;C07C2/24;C07C2/26
Applicant(s) Name
申请人
Phillips Petroleum Co.
Address 地址
Inventor(s) Name 发明人 J.W. Freeman;B.E. Kreischer;W.M. Ewert et.al
Attorney & Agent 代理人 chen jizhuang
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